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Beilstein J. Org. Chem. 2016, 12, 1111–1121, doi:10.3762/bjoc.12.107
Graphical Abstract
Figure 1: Modular concept for manzacidin synthesis based on a Tsuji–Trost coupling of joint intermediate 5.
Scheme 1: General concept for heterocycles synthesis based on a nucleophilic addition and Tsuji–Trost couplin...
Scheme 2: Synthesis of homoallylic alcohol 12 by multi-component reactions.
Scheme 3: Preparation of urea-type cyclization precursor 19.
Scheme 4: Stereodivergent synthesis of 1,3-syn- and anti-tetrahydropyrimidinones [31].
Scheme 5: Stereoselective synthesis of all possible stereoisomers of the manzacidin core amine by asymmetric ...
Scheme 6: Synthesis of the authentic cyclization precursor 5.
Figure 2: X-ray structure of 39.
Scheme 7: Divergent Tsuji–Trost coupling and completion of the synthesis of authentic pyrimidinones 3 and 4.
Beilstein J. Org. Chem. 2014, 10, 2774–2782, doi:10.3762/bjoc.10.294
Figure 1: (a), (b) Two distinguishable packings of alkyl chains on cutouts of graphite are shown with the car...
Figure 2: (a)–(c) Schematic structure of a hexagonal shape-persistent macrocycle with extraannular alkoxy cha...
Figure 3: (a)–(c) Shape-persistent macrocycles with an empty cavity (1), an apolar interior (undecyl diether ...
Figure 4: Scanning tunneling microscopy images and supramolecular models of (a)–(c) porous (= polymorph A) an...
Figure 5: (a)–(e): Schematic structure of the shape-persistent macrocycle 1 (as a representative of the serie...